亚甲蓝
电解质
化学
水溶液
次氯酸盐
无机化学
次氯酸钠
氯
氯化物
动力学
亚甲基
有机化学
催化作用
电极
光催化
物理
物理化学
量子力学
作者
Ruoying Zhu,Yuru Shen,Jin Zhao,Guigang Shi,Jianyong Liu,Junping Cao
标识
DOI:10.1177/00405175221143522
摘要
Electrolytic active water was prepared by electrolytic treatment of sodium chloride aqueous solution using a self-made device. In order to investigate the properties of electrolytic active water , the pH value, available chlorine contents and decolorization ability on methylene blue solution were tested and compared with that of sodium hypochlorite aqueous solution. Experimental results showed that the electrolytic active water has higher oxidation capacity and decolorization efficiency for methylene blue compared with sodium hypochlorite solution, implying maybe other reactive oxygen species components besides hypochlorite existed in the electrolytic active water. The electrolytic active water was stable under long-term storage, and mechanical force with oxidation activity did not decrease. In addition, the decolorization kinetics of methylene blue in the electrolytic active water was explored, and it was found that, in general, the decolorization reaction of methylene blue in electrolytic active water was consistent with the first-order reaction kinetics model, but when the pH value of electrolytic active water solution was weakly alkaline or neutral, the decolorization reaction of methylene blue was closer to the second-order reaction kinetics model.
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