Cellulose nanofiber-poly(ethylene terephthalate) nanocomposite membrane from waste materials for treatment of petroleum industry wastewater

Petroleum industry wastewater contains high level of crude oil and other types of organic substances that can cause immense harm to the agriculture, aquatic as well as terrestrial organisms. Organic solvent resistance of membranes is very important to treat such wastewater that contains high level of organic pollutants. This work reports the designing of a superhydrophilic and organic solvent resistant nanocomposite membrane using waste bottles made of poly(ethylene terephthalate) (PET) and cellulosic papers. Using in-situ synthesized cellulose nanofibers we could successfully fabricate porous membranes which is not possible for bare PET matrix using water as nonsolvent. Thus, we could successfully replace methanol which was used as a suitable non-solvent in earlier reports by distilled water. We successfully used the membrane for separation of synthetic crude oil-water emulsion. The membrane showed permeability up to 98 Lm-2h-1 applying pressure of 1.5 bar. The membrane also achieved removal of more than 97 % of organic substances from a crude oil-water emulsion system. The optimum membrane also showed good thermal stability with initial degradation temperature ∼350 °C and tensile strength of 0.86 MPa. The antimicrobial property of the nanocomposite membranes could be achieved by coating its surface with carbon dots rooted graphene oxide.