Solar photovoltaic refrigeration system coupled with a flexible, cost-effective and high-energy-density chemisorption cold energy storage module

Owing to the environmental pollution and high costs associated with lead-acid batteries, this paper proposes a solar photovoltaic (PV) refrigeration system coupled with a flexible, cost-effective and high-energy-density chemisorption cold energy storage module. Its operation mode includes daytime solar PV refrigeration/cold energy charging mode and nighttime cold energy discharging mode. A novel composite sorbent SrCl2 is developed using expanded natural graphite as matrix and carbon coated aluminum as additive, exhibiting superior heat and mass transfer performance. A sorbent performance test bench is constructed, demonstrating that the cold energy storage density reaches 503.6 kJ/kg at an evaporating temperature of −15 °C, 1.5 times of ice storage. Compression-assisted desorption is adopted to regulate desorption temperature, so that 75–90 °C solar hot water from low-cost non-concentrating solar collectors can be utilized as the driving heat source. For an evaporating temperature of −10 °C and a solar hot water temperature of 90 °C, the electrical coefficient of performance for cold energy storage unit reaches 3.72, representing a 33 % improvement compared to conventional solar PV refrigeration systems. This novel system features characteristics such as low cost, high efficiency and eco-friendliness, offering a promising solution for solar refrigeration.