支柱
卟啉
多孔性
材料科学
纳米技术
结晶学
化学
光化学
复合材料
工程类
结构工程
作者
Jacob A. Johnson,Qipu Lin,Lai Chin Wu,Nasrat Obaidi,Zachary L. Olson,Tyler C. Reeson,Yu Sheng Chen,Jian Zhang
摘要
A "pillar-free", highly porous metalloporphyrinic framework (UNLPF-1) exhibiting eclipsed porphyrin arrays has been constructed from an octacarboxylate ligand connected with paddlewheel secondary building units. UNLPF-1 possesses two types of open metal sites and exhibits an efficient selectivity toward capture of CO2 over N2.
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(2025-6-4)
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