Mercury(编程语言)
荧光
化学
离子
分子
光化学
选择性
小分子
环境化学
分析化学(期刊)
无机化学
有机化学
物理
程序设计语言
催化作用
量子力学
生物化学
计算机科学
作者
Shudi Liu,Xia Zhang,Guangdong Bai,Panpan Zhou,Li Zhang,Qingzhong Li,Renjie Zhang,Lingxin Chen,Liangwei Zhang
标识
DOI:10.1016/j.jhazmat.2021.127701
摘要
Development of new fluorescent probes for mercury ion analysis in environmental or living organism is undergoing quick growth due to its detrimental toxicity to environmental safety, ecological security, and human being. However, in most cases, the industrial waste water is acidic whereas it remains a great challenge to real-time monitor mercury ion directly at low pH using small molecule fluorescence probe. In this study, we have successfully designed and synthesized the Naph (1, 8-Naphthalimide derivative) -based small molecule probe termed as Naph-NSS capable of monitoring mercury ion in a broad range at low pH (from 2.0 to 7.0). The solid spectral studies demonstrated the high sensitivity and selectivity of the probe towards mercury ion among various species. After binding with Hg2+, the fluorescence of Naph-NSS greatly enhanced, and the mechanism of which was investigated by DFT studies. The probe was able to be loaded on paper strip for instant and fast detection of mercury ions. In addition, the probe is also suitable for detection of mercury ion in environmental samples, living cells and in vivo.
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