土壤水分
化学
碳酸氢盐
环境化学
铬
阳离子交换容量
总有机碳
土壤pH值
动力学
溶解有机碳
土壤科学
环境科学
量子力学
物理
有机化学
作者
Chia-Yu Yang,Yan-Lin Tseng,Zeng-Yei Hseu
出处
期刊:Water
[MDPI AG]
日期:2022-02-13
卷期号:14 (4): 570-570
被引量:1
摘要
Chromium (Cr)(VI) is carcinogenic; thus, the excessive presence of Cr(VI) in soils can pose potential risks to water quality, food safety, and human health. The kinetics of Cr(VI) reduction in soils are important for assessing the fate of Cr in the environment. The present study tested physio-chemical and microbial properties in twenty-eight agricultural soils collected in Taiwan to evaluate the relationship between the reduction rate of Cr(VI) and soil properties, using 49-day incubation at 25 °C. At the beginning of incubation, 100 mg Cr(VI) kg−1 was spiked into the soils. The reduction of Cr(VI) was described by first-order kinetics at a significant level (p < 0.05) for the tested soils. The rate constant (k) of Cr(VI) reduction ranged from 0.01 to 4.21 day−1. In addition, the k value significantly increased with organic carbon (OC) and cation exchange capacity, but significantly decreased with increasing pH and dithionite-citrate-bicarbonate extractable Mn (Mnd). However, a predictive model using stepwise regression analysis indicated that the k value of the kinetics was controlled by OC, dissolved organic carbon (DOC), and Mnd, thereby identifying the complex interactions between Cr(VI) reduction and soil factors in the humid tropics.
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