电荷(物理)
分子内力
光化学
接受者
化学物理
量子产额
激发态
电子供体
荧光
电子转移
原子物理学
化学
物理
凝聚态物理
立体化学
量子力学
有机化学
催化作用
作者
Sirui Yang,Chen Cao,Jiayu Li,Ziqi Deng,Shao‐Fei Ni,Jing‐Xin Jian,Qing‐Xiao Tong,Li Dang,Ming‐De Li
标识
DOI:10.1021/acs.jpcc.1c09884
摘要
Charge transfer plays an important role in photophysical and photochemical reactions. However, the factors affecting the excited charge-transfer state are unclear. Here, two donor−π–acceptor dyads with an excellent blue fluorescence quantum yield are designed by integrating 1,2-diphenylphenanthroimidazole (PPI) as an electron donor and 1,2,4-triazolopyridine (TP) as an electron acceptor through phenyl (P) bridges. In the solvents dichloromethane (DCM) and dimethyl formamide (DMF), the dynamics of intramolecular charge transfer (ICT) of the two dyads (TP-P-PPI and TP-P-P-PPI) is located at the Marcus normal region, while the dynamics of charge recombination (CR) is situated at the Marcus inverted region. Therefore, TP-P-P-PPI with a long π-chain exhibits a longer lifetime of ICT but a shorter lifetime of CR than TP-P-PPI does with a short π-chain. In contrast, when the two dyads are spin-coated into a film, the dynamics of ICT and CR processes of the two dyads are restored to be positively correlated with the π-chain length because of the inhibition of intramolecular torsion between PPI and TP in the excited state of the film. This work demonstrates a specific approach via the molecular torsion to tune the dynamics of the ICT and CR among donor−π–acceptor systems.
科研通智能强力驱动
Strongly Powered by AbleSci AI