Recent advances in photochemical rearrangements involving diradicals

innovative diradical strategies. Looking forward, we identify three key growth areas: (1) synergistic integration of energy transfer catalysis with diradical reactivity, (2) the development of sustainable photochemical rearrangements powered by visible light, and (3) implementation of computational tools for mechanistic prediction and reaction optimization This review serves both as an authoritative reference on fundamental mechanisms and as a strategic guide for future innovation, bridging the gap between theoretical understanding and practical synthetic applications in this rapidly evolving field.