Alcohol-solvothermal syntheses, crystal structures and photocatalytic properties of tin selenides with polyselenide ligands

New polyselenidostannates with Se₂²⁻ or Se₄²⁻ polyselenide ligands, [TM(en)₃]Sn₃Se₆(Se₂) (1–3), [Ni(en)₃]Sn₃Se_7.5 (4) and [TM(en)₃][Sn(Se₄)₃] (5–8), were prepared by alcohol-solvothermal methods.