硫化物
硫黄
化学
无机化学
膜
原电池
电化学
Nafion公司
阳极
质子交换膜燃料电池
电极
核化学
有机化学
生物化学
物理化学
作者
El-Zemity Saad,T.M. Zewail,A. A. Zatout,E.-S. Z. El-Ashtoukhy,M.H. Abdel‐Aziz
标识
DOI:10.1016/j.jiec.2020.11.008
摘要
In this work a two-compartment galvanic cell with two graphite rod electrodes and two types of cation exchange membranes: namely the Nafion membrane and synthetic fabric membrane is tested in treating sulfide containing wastes and recovery of elemental sulfur. The cell reactions are sulfide oxidation at the anode and chromium (VI) reduction at the cathode. The effect of different parameters such as external resistance, initial concentration of K2Cr2O7 solution, H2SO4 concentration, and initial concentration of Na2S, the pH of the solution, NaCl concentration, and temperature of the solution is investigated. The cell performance as a reactor and as an energy converter is expressed in terms of % sulfide removal and current-voltage plots, respectively. Depending on the effects of the aforementioned factors, the optimal conditions that give the highest performance were determined, and then the cell was tested on real wastes from refinery processing at those conditions. The cell showed high selectivity in sulfide removal and sulfur recovery with almost no interference with other contaminants.
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