双金属片
材料科学
纳米材料
纳米材料基催化剂
催化作用
纳米颗粒
多孔性
基质(水族馆)
纳米技术
硅酸铝
化学工程
碳纳米管
电催化剂
制作
电化学
电极
化学
冶金
复合材料
有机化学
金属
工程类
医学
海洋学
替代医学
物理化学
病理
地质学
作者
Fatemeh Amiripour,Shahram Ghasemi,Seyed Naser Azizi
标识
DOI:10.1016/j.apsusc.2020.147827
摘要
Functionalized porous nanomaterials have been introduced as novel substrates with high surface area and large porosity for the construction of efficient catalysts in sensors. In this regard, nano X zeolite (NX), as a kind of aluminosilicate framework material, can be used as a hosting material for nanocatalysts in the design and fabrication of electrochemical sensors. Herein, a sensor based on multi-walled carbon nanotube (MWCNT) and NX material as a substrate for AuNi bimetallic nanoparticles obtained from agro-waste stem sweep was fabricated to detect nanomolar concenteration of glucose. The catalyst has provided a desired analytical performance for the glucose sensor with low limit of detection (0.063 µM) in the linear range of 1–1900 µM and sensitivity of 662.93 µA mM−1. The results depend on the presence of NX in the sensor and confirm the preference of a porous host existence for the AuNi catalyst in the sensing process. In AuNi/NX/MWCNT electrocatalyst, the disaggregation of Au nanoparticles by decorating on sacrificial Ni and the creation of abundant active sites through NX make the acceptable results for non-enzymatic detection of glucose in the human serum samples.
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