Thermodynamics of Ga2O3 Heteroepitaxy and Material Growth Via Metal Organic Chemical Vapor Deposition

Heteroepitaxy of gallium oxide (Ga₂O₃) is gaining popularity to address the absence of p-type doping, limited thermal conductivity of Ga₂O₃ epilayers, and toward realizing high-quality p-n heterojunction. During the growth of β-Ga₂O₃ on 4H-SiC (0001) substrates using metal-organic chemical vapor deposition, we observed formation of incomplete, misoriented particles when the layer was grown at a temperature between 650 °C and 750 °C. We propose a thermodynamic model for Ga₂O₃ heteroepitaxy on foreign substrates which shows that the energy cost of growing β-Ga₂O₃ on 4H-SiC is slightly lower as compared to sapphire substrates, suggesting similar high-temperature growth as sapphire, typically in the range of 850 °C-950 °C, that can be used for the growth of β-Ga₂O₃ on SiC. A two-step modified growth method was developed where the nucleation layer was grown at 750 °C followed by a buffer layer grown at various temperatures from 920 °C to 950 °C. 2θ-ω scan of X-ray diffraction (XRD) and transmission electron microscope images confirm the β-polymorph of Ga₂O₃ with dominant peaks in the (-201) direction. The buffer layer grown at 950 °C using a "ramp-growth" technique exhibits root-mean-square surface roughness of 3 nm and full width of half maxima of XRD rocking curve as low as 0.79°, comparable to the most mature β-Ga₂O₃ heteroepitaxy on sapphire, as predicted by the thermodynamic model. Finally, the interface energy of an average Ga₂O₃ island grown on 4H-SiC is calculated to be 0.2 J/m² from the cross-section scanning transmission electron microscope image, following the Wulff-Kaishew theorem of the equilibrium island shape.