电致变色
非阻塞I/O
材料科学
薄膜
溅射沉积
分压
分析化学(期刊)
溅射
氧气
结晶度
拉曼光谱
光学
纳米技术
化学
电极
复合材料
物理化学
催化作用
生物化学
色谱法
物理
有机化学
作者
Yongkang Tang,Hongxue Shen,Tianqi Wang,Saiao Peng,Kewu Jin,Qian Qian,Gang Li,Gan Zhi-ping
标识
DOI:10.1016/j.tsf.2023.139754
摘要
Electrochromic NiO thin films were prepared by the DC magnetron sputtering method under different oxygen partial pressure conditions. The phase, microstructure, ions moving behavior, and electrochromic properties of NiO films were investigated by X-ray diffraction, field emission scanning electron microscopy, Raman spectrometer, electrochemical workstation, and ultraviolet-visible-infrared spectrophotometer, respectively. The sample prepared under middle oxygen partial pressure shows better electrochromic properties after the coloring and bleaching cycles. The coloring or bleaching time is 1∼4 s, the optical modulation amplitude is 40.6% and the coloration efficiency is 37.63 cm2·C−1. The oxygen partial pressure may mainly affect the crystallinity of the samples, resulting in different charge-transfer resistance which is related to the reactions of coloring or irreversible non-coloring. Further, the Li+ can be stored in the volume space and surface space of NiO thin films, and the grain boundary and lattice gap are two existent paths for Li+transmission and storage.
科研通智能强力驱动
Strongly Powered by AbleSci AI