Fullerenens and metallofullerenes represented by C60 has been a hot research of science field in recent years.This article introduced the synthesis of four different types of metallofullerene complexes: endohedral metallofullerenes,simple circumscribed type of metallofullerenes complexes,η2-metallofullerenes complexes and metallofullerene group complexes,especially the research progress on metallofullerene group complexes.