ChemInform Abstract: One‐Pot Sequential Organocatalysis: Highly Stereoselective Synthesis of Trisubstituted Cyclohexanols.

Abstract The present protocol involves a quinidine thiourea‐catalyzed tandem Henry—Michael reaction between aliphatic and aromatic oxoheptenals (I) and (IV) and nitromethane (II), followed by a tetramethyl guanidine‐catalyzed tandem retro‐Henry—Henry reaction on the reaction products of the tandem Henry—Michael reaction.