太赫兹辐射
机械化学
材料科学
分子振动
机械合成
光谱学
太赫兹光谱与技术
化学物理
表征(材料科学)
红外光谱学
纳米技术
分子物理学
化学
光电子学
分子
复合材料
有机化学
物理
量子力学
球磨机
作者
Wei Zhang,Jefferson Maul,Diana Vulpe,Peyman Z. Moghadam,David Fairen‐Jimenez,Daniel M. Mittleman,J. Axel Zeitler,Alessandro Erba,Michael T. Ruggiero
标识
DOI:10.1021/acs.jpcc.8b08334
摘要
The identification and characterization of low-frequency vibrational motions of metal–organic frameworks (MOFs) allows for a better understanding of their mechanical and structural response upon perturbation by external stimuli such as temperature, pressure, and adsorption. Here, we describe the combination of temperature- and pressure-dependent terahertz spectroscopy measurements with quantum mechanical simulations to measure and assign specific low-frequency vibrational modes that directly drive the mechanochemical properties of this important class of porous materials. More specifically, we identify intense spectral features in the terahertz region of the vibrational spectrum of ZIF-8 which are directly connected to its mechanochemical response. In particular, we find that the mechanical compressibility of pristine ZIF-8 follows a peculiar nonlinear trend upon pressure: its bulk modulus initially increases up to 0.1 GPa and decreases at higher pressures, which is simultaneously reflected in the terahertz vibrational spectra. This work highlights the interplay between structural, vibrational, and mechanochemical phenomena, all of which are key to the effective exploitation of MOFs. The importance of terahertz vibrational motions on the function of MOFs is demonstrated, and a method is presented for their measurement and interpretation, which can be applied widely to any supramolecular material.
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