异烟酰胺
乙腈
四氟硼酸盐
化学
吡啶
分子
氢键
结晶学
配体(生物化学)
铜
药物化学
立体化学
有机化学
受体
离子液体
生物化学
催化作用
作者
Gerhard Baum,Alexander J. Blake,Dieter Fenske,Peter Hubberstey,Carine Julio,M.A. Withersby
标识
DOI:10.1107/s0108270102018097
摘要
Molecules of the title compound, [Cu(C(2)H(3)N)(C(11)H(9)N(5))(C(6)H(6)N(2)O)](BF(4))(2).2C(2)H(3)N, comprise (acetonitrile)[2,6-bis(pyrazol-1-yl)pyridine](isonicotinamide)copper(II) cations, tetrafluoroborate anions and lattice acetonitrile molecules. The cations have distorted square-pyramidal geometries in which the N(3)-donor, viz. 2,6-bis(pyrazol-1-yl)pyridine, and the N-donor, viz. the isonicotinamide ligand, occupy the four basal positions, with the coordinated acetonitrile N-donor atom occupying the apical position. Pairs of cations are linked by N-H.F hydrogen bonds through tetrafluoroborate anions, forming centrosymmetric dimers, which are further linked by C-H.O hydrogen bonds into two-dimensional undulating sheets, three of which interpenetrate to generate a two-dimensional network.
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