醋酸纤维素
微晶纤维素
材料科学
化学工程
乙基纤维素
结晶度
热稳定性
纤维素纤维
水解
作者
James E. Sealey,Gamini Samaranayake,Jason G. Todd,Wolfgang G. Glasser
标识
DOI:10.1002/(sici)1099-0488(19960715)34:9<1613::aid-polb10>3.0.co;2-a
摘要
Cellulose esters with linear aliphatic acyl substituents ranging in size from C12 (lauric acid) to C20 (eicosanoic acid) were prepared in homogeneous solution (DMAc/LiCl) using a novel synthetic method based on the use of a mixed p-toluenesulfonic/carboxylic acid anhydride. The resulting waxy cellulose esters had a high degree of substitution (DS), between 2.8 and 2.9, and showed little degradation. Thermal analysis of these cellulose derivatives by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA) revealed a series of transitions that represented motion by both ester substituents and cellulosic main chain. Broad crystallization and melting transitions attributed to side-chain crystallinity were observed in the range between −19 and +55°C; these side-chain Tm and Tc transition temperatures increased by 10°C per carbon atom of the ester substituent. The Tg of these derivatives increased linearly with increasing substituent size from 94°C for C12 (cellulose laurate) to 134°C for C20 (cellulose eicosanoate). Evidence of “main-chain” crystallization was not observed for these samples, except in the case of peracetylated C12 and C14 esters, which had Tm values of 96°C and 107°C, respectively. © 1996 John Wiley & Sons, Inc.
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