光催化
铬
可见光谱
兴奋剂
吸收光谱法
密度泛函理论
紫外线
紫外可见光谱
吸收(声学)
材料科学
紫外线
光谱学
X射线光电子能谱
无机化学
化学
光化学
化学工程
冶金
光电子学
催化作用
光学
计算化学
有机化学
复合材料
物理
量子力学
工程类
作者
J.W. Liu,G. Chen,Z.H. Li,Zhiguo Zhang
标识
DOI:10.1016/j.jssc.2006.08.014
摘要
Cr-doped SrTi1−xCrxO3 (x=0.00, 0.02, 0.05, 0.10) powders, prepared by solvothermal method, were further characterized by ultraviolet–visible (UV–vis) absorption spectroscopy. The UV–vis spectra indicate that the SrTi1−xCrxO3 powders can absorb not only UV light like pure SrTiO3 powder but also the visible-light spectrum (λ>420 nm). The results of density functional theory (DFT) calculation illuminate that the visible-light absorption bands in the SrTi1−xCrxO3 catalyst are attributed to the band transition from the Cr 3d to the Cr 3d+Ti 3d hybrid orbital. The photocatalytic activities of chromium-doped SrTiO3 both under UV and visible light are increased with the increase in the amounts of chromium.
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