Iodine-Copper(II) Acetate

(I2) [7553-56-2] I2 (MW 253.80) InChI = 1S/I2/c1-2 InChIKey = PNDPGZBMCMUPRI-UHFFFAOYSA-N (Cu(OAc)2) [142-71-2] C4H6CuO4 (MW 181.65) InChI = 1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 InChIKey = OPQARKPSCNTWTJ-UHFFFAOYSA-L (Cu(OAc)2·H2O) [6046-93-1] C4H8CuO5 (MW 199.67) InChI = 1S/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2 InChIKey = NWFNSTOSIVLCJA-UHFFFAOYSA-L (iodination of ketones, alkenes, and aromatic compounds; oxidation of cycloalkenes and alkyl-substituted ketones) Physical Data: Cu(OAc)2·H2O: mp 115 °C; d 1.882 g cm−3. Solubility: Cu(OAc)2·H2O: sol H2O, ethanol; slightly sol ether, glycerol. Form Supplied in: Cu(OAc)2·H2O: dark blue–green solid. Handling, Storage, and Precautions: both reagents are toxic and should be handled in a fume hood.