三乙醇胺
乙二胺
二乙烯三胺
纳米棒
材料科学
成核
溶剂
化学工程
水溶液
溶剂热合成
无机化学
纳米技术
化学
有机化学
分析化学(期刊)
复合材料
工程类
作者
F. Vaquero,R.M. Navarro,J.L.G. Fierro
标识
DOI:10.1016/j.apcatb.2016.10.073
摘要
CdS crystals with different morphologies, nanorods, sheets, microspheres and irregular particles have been obtained by changing the solvothermal solvent (ethylenediamine, diethylenetriamine, triethanolamine and ethanol). Characteristics of the solvothermal solvents, such as dielectric constant, ion-coordination and length of an atomic chain, have influence on the nucleation and growth of CdS crystals. The differences in the morphological and structural characteristics of the CdS crystals have strong influence on their photophysical properties as well as in their photoactivity for hydrogen production under visible light from aqueous solutions containing Na2SO3 and Na2S as sacrificial electron donor agents. The hydrogen production rate on CdS samples decreases in the order: nanorods (ethylenediamine) > sheets (diethylenetriamine) > irregular particles (triethanolamine) >> microspheres (ethanol). Variations in photoactivity were analysed taking into account the changes in the morphology, structure, surface and light absorption ability of CdS crystals.
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