Ternary blends from biological poly(3-hydroxybutyrate-co-4-hydroxyvalerate), poly(L-lactic acid), and poly(vinyl acetate) with balanced properties

Herein, poly(3-hydroxybutyrate-co-4-hydroxyvalerate) (P34HB), poly (L-lactic acid) (PLA), and poly(vinyl acetate) (PVAc) were initially melt compounded to prepare a ternary blend with balanced properties. Further, the miscibility, phase morphology, thermal and crystallization behaviors, and rheological and mechanical properties of the blends were studied. The dynamic mechanical analysis (DMA) results indicated that P34HB and PLA were partially miscible; however, PVAc showed full miscibility with PLA and P34HB. PVAc would selectively disperse in the PLA phase when considering low content, whereas it would gradually diffuse into the P34HB phase with the increasing PVAc concentration. A phase-separated morphology was observed for all the blends using scanning electron microscopy (SEM), and the diameters of the dispersed phases increased with the increasing PVAc concentration. The crystallization of P34HB was enhanced by the presence of PLA alone and was restrained by the simultaneous incorporation of PVAc and PLA. The rheological properties of P34HB were significantly improved because of the PVAc phase. Unexpectedly, the toughness and stiffness of the P34HB in ternary blends clearly improved because of the incorporation of PLA and PVAc.