阴极
电化学
化学
材料科学
化学工程
电极
粒子(生态学)
分析化学(期刊)
电解质
作者
Wei Xu,Yi-Ge Zhou,Jun Chen,Ye Tian,Li Yang,Shouyi Yin,Guoqiang Zou,Hongshuai Hou,Xiaobo Ji
标识
DOI:10.1016/j.jpowsour.2021.230228
摘要
Abstract An electrochemical collision method focusing on individual particles is applied to investigate the LiNi0.8Mn0.1Co0.1O2 for direct and accurate information about the ions migration process. For the first time, two types of unique current signals including trapezoid-like signals and wider-wave signals are observed with the increase of particle sizes, except for the acquainted spike-like signals with a sharp rise and a slow decay. The trapezoid-like signals started with a slow rise following by a steady platform and a slow decay, revealing an out-of-sync reaction at the beginning and a subsequent interface traversing and internal ion diffusion jointly controlled ions migration process in the particle. The wider-wave signals with a slower rise and a much slower decay are acquired from particles with the largest size, showing the slowest kinetics during the whole reaction process in the particle.
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