堆栈(抽象数据类型)
材料科学
电解质
温度梯度
固体氧化物燃料电池
阳极
阴极
氧化物
压力(语言学)
热的
复合材料
化学
电极
热力学
冶金
量子力学
物理
语言学
哲学
物理化学
计算机科学
程序设计语言
作者
Jianmin Zheng,Liusheng Xiao,Ming Chen,Jinliang Yuan
出处
期刊:ECS transactions
[The Electrochemical Society]
日期:2021-07-07
卷期号:103 (1): 767-784
被引量:1
标识
DOI:10.1149/10301.0767ecst
摘要
Typical operating temperature for a solid oxide fuel cell (SOFC) ranges from 700°C to 800°C. A large temperature gradient and thermal stress are induced by internal losses and electro-chemical reactions, resulting in significant structural damage and performance degradation of a SOFC stack, which has become a hindrance to its applications. In this study, a three-dimensional multi-physics CFD model is developed and employed to study the temperature and thermal stress distribution of a planar SOFC stack, then effects of the structure design parameters are investigated, including the flow channel arrangement (i.e., co- and cross-flow) and thickness of the electrolyte layer. The stack modeled is composed of three-unit cells, metallic interconnect layers, sealing components, and anode/cathode current collectors. The simulation results show that the temperature difference in the co-flow case is smaller and the thermal stress is lower than those predicted in the cross-flow. The overall performance of the stack improves as the thickness of the electrolyte layer decreases, but the temperature and its gradient inside the stack become higher. In addition, a large temperature gradient is observed inside the thin electrolyte layer, which leads to a significant increase of the thermal stress. The findings and the research methods in this study can be applied to design and optimize the stack structures by considering the temperature and the thermal stress distribution.
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