材料科学
丙烷
微型多孔材料
催化作用
原位
烧结
贵金属
化学工程
多孔性
氧化物
金属
无机化学
有机化学
冶金
复合材料
工程类
化学
作者
C.N.R. Rao,Peng Cheng,Honggen Peng,Li Zhang,Wenming Liu,Xiang Wang,Ning Zhang,Peng Wu
标识
DOI:10.1021/acsami.8b01450
摘要
Most of the industrial and environmental catalytic reactions are operated at high temperature for a long time, and the sintering of the active centers is the main factor leading to catalysts deactivation, especially for noble metal catalysts. Herein we develop a dual confinement (enhanced metal-oxide interaction and the porous shell confinement) strategy to prepare Pd–Sn pseudo solid solution and in situ embedded in microporous silica for the first time and showed superior catalytic performance for CO and propane total oxidation (two main vehicle emission gases), even stored more than 640 days.
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