心环烯
富勒烯
纳米技术
材料科学
模块化(生物学)
金属有机骨架
化学
吸附
有机化学
遗传学
生物
作者
Allison M. Rice,Ekaterina A. Dolgopolova,Natalia B. Shustova
标识
DOI:10.1021/acs.chemmater.7b02245
摘要
Merging the intrinsic properties of fullerene (buckyball) and corannulene (buckybowl) derivatives with the inherent properties of crystalline metal- and covalent-organic frameworks (MOFs and COFs), including their modularity, porosity, versatility, high surface area, and structural tunability, opens a pathway to unlock a novel class of fulleretic materials. Despite the great interest in MOFs and COFs, as well as fullerene derivatives, this perspective is the first overview focusing solely on crystalline fullerene- and corannulene-containing frameworks, highlighting their potential contributions in the fields of optoelectronic devices, electrodes, and photosensitizers. We revealed a dual role of fullerene- and corannulene-containing building blocks showing their versatility to act as either a framework linker or a guest inside the pores. This perspective encompasses a rising new field in which fulleretic crystalline frameworks are not only structural and synthetic masterpieces but also valuable potential materials to the ever-expanding technological landscape.
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