Enhancing Hole Transport Uniformity for Efficient Inverted Perovskite Solar Cells through Optimizing Buried Interface Contacts and Suppressing Interface Recombination

Abstract [4‐(3,6‐dimethyl‐9H‐carbazol‐9yl)butyl]phosphonic acid (Me‐4PACz) self‐assembly material has been recognized as a highly effective approach for mitigating nickel oxide (NiO x ) surface‐related challenges in inverted perovskite solar cells (IPSCs). However, its uneven film generation and failure to effectively passivate the buried interface defects limit the device‘s performance improvement potential. Herein, p‐xylylenediphosphonic acid (p‐XPA) containing bilateral phosphate groups (−PO 3 H 2 ) is introduced as an interface layer between the NiO x /Me‐4PACz and the perovskite layer. P‐XPA can flatten the surface of hole transport layer and optimize interface contact. Meanwhile, p‐XPA achieves better energy level alignment and promotes interfacial hole transport. In addition, the bilateral −PO 3 H 2 of p‐XPA can chelate with Pb 2+ and form hydrogen bond with FA + (formamidinium cation), thereby suppressing buried interface non‐radiative recombination loss. Consequently, the IPSC with p‐XPA buried interface modification achieves champion power conversion efficiency of 25.87 % (certified at 25.45 %) at laboratory scale (0.0448 cm 2 ). The encapsulated target device exhibits better operational stability. Even after 1100 hours of maximum power point tracking at 50 °C, its efficiency remains at an impressive 82.7 % of the initial efficiency. Molecules featuring bilateral passivation groups optimize interfacial contact and inhibit interfacial recombination, providing an effective approach to enhancing the stability and efficiency of devices.