Transfer-Length Method Measurements Under Variable Illumination to Investigate Hole- Selective Passivating Contacts on c-Si(p) and c-Si(n) Wafers

类型(生物学) 薄脆饼 符号 反向 材料科学 硅 物理 数学 分析化学(期刊) 光电子学 化学 几何学 有机化学 算术 生物 生态学
作者
Laurie‐Lou Senaud,Luca Antognini,Gabriel Christmann,Mathieu Boccard,Matthieu Despeisse,Christophe Ballif,Bertrand Paviet‐Salomon
出处
期刊:IEEE Journal of Photovoltaics [Institute of Electrical and Electronics Engineers]
卷期号:13 (3): 422-431 被引量:8
标识
DOI:10.1109/jphotov.2023.3242131
摘要

In this article, transfer length method (TLM) measurements under variable illumination are applied to study p-type carrier selective passivating contacts (CSPCs) employed in the silicon heterojunction (SHJ) technology. In the case of p-type CSPCs deposited on p-type crystalline silicon (c-Si(p)) wafers, we demonstrate that illumination has a strong impact on the contact resistivity ( $\rho _{c}$ ) value, as demonstrated in our previous contribution in the case of n-type CSPCs on c-Si(n). Noticeably, it was again found that $\rho _{c}$ increases and that the c-Si sheet resistance ( $R_\text{sh}$ ) decreases with the illumination. In addition, we demonstrate that $\rho _{c}$ is impacted differently by illumination depending on the doping of the p-type thin hydrogenated silicon layer. Then, we investigate and discuss the applicability of TLM measurements under illumination to measure p-type CSPCs deposited on their inverse type c-Si(n) wafers. First, performing TLM measurement in dark conditions of such samples allow one to measure $R_\text{sh}$ values with orders of magnitude corresponding to the c-Si(n) inversion layer one. Second, we demonstrate that under illumination, the lateral transport inside the c-Si(n) bulk is supported by the electrons thanks to two experimental evidences, i.e., that the $R_\text{sh}$ behavior as a function of injection behaves as the one of electrons and that an electron transport inside the c-Si(n) wafer in the presence of two p-type CSPCs TLM pads can only be mediated thanks to photogeneration under one pad and recombination under the other. These results provide additional understandings of the TLM measurement under illumination as well as strong insights for the investigation of carriers' transport and electrical losses in CSPCs solar cells.
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