Synthesis of sp2 Carbon‐Conjugated Covalent Organic Framework Thin‐Films via Copper‐Surface‐Mediated Knoevenagel Polycondensation

Abstract sp 2 carbon‐conjugated covalent organic framework (sp 2 c‐COF) featured with high π‐conjugation, high chemical stabilities, and designable chemical structures, are thus promising for applications including adsorption and separation, optoelectronic devices, and catalysis. For the most of these applications, large‐area and continuous films are required. However, due to the needs of harsh conditions in the formation of CC bonds, classical interfacial methodologies are challenged in the synthesis of sp 2 c‐COFs films. Herein, a novel and robust interfacial method namely copper‐surface‐mediated Knoevenagel polycondensation (Cu‐SMKP), is shown for scalable synthesis of sp 2 c‐COF films on various Cu substrates. Using this approach, large‐area and continuous sp 2 c‐COF films could be prepared on various complicated Cu surfaces with thickness from tens to hundreds of nanometers. The resultant sp 2 c‐COF films on Cu substrate could be used directly as functional electrode for extraction of uranium from spiked seawater, which gives an exceptionally uptake capacity of 2475 mg g −1 . These results delineate significant synthetic advances in sp 2 c‐COF films and implemented them as functional electrodes for uranyl capture.