发光
材料科学
荧光
检出限
金属有机骨架
猝灭(荧光)
扫描电子显微镜
光谱学
混合材料
纳米技术
化学工程
化学
复合材料
光电子学
光学
色谱法
物理化学
物理
量子力学
工程类
吸附
作者
Lingyan Pang,Hao Zhang,Zhengnan Qian,Hafiz Akif Munir,Junqi Li,Hui Liu
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2023-10-31
卷期号:6 (21): 20220-20230
标识
DOI:10.1021/acsanm.3c04035
摘要
The rapid detection of antibiotics in water plays a crucial role in environmental monitoring. This paper focuses on the fabrication and synthesis of an Eu–Al-MOG (metal–organic gel, MOG) nanoscale luminescent material using a combination of sol–gel and curing methods, which is suitable for the efficient and repetitive detection of doxycycline (DOX). Structural analysis, including X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (EDS), verifies the homogeneous and close combination of the luminescent material [Eu-MOF (MOF = metal–organic framework)] and host material (Al-MOG) within the Eu–Al-MOG composite. Eu–Al-MOG exhibits a fluorescence emission at 280 nm, facilitating effective DOX detection through fluorescence quenching. The achieved lowest limit of detection is 0.77 μM. Benefiting from the Al-MOG matrix, the fluorescence emission intensity could exhibit consistent stability during 90 min of continuous detection. In repeated detections, the mass could be preserved, and the emission intensity could be easily recovered through simple rinsing, demonstrating excellent stability and reusability. The detection mechanism of DOX is analyzed as the internal filtration effect and photoinduced electron transfer through fluorescence lifetimes, UV–vis absorption spectra, and other analyses. Furthermore, the study investigates the formation mechanism of Eu2–Al2-MOG composites and proposes an optimal synthesis strategy for their preparation. This work introduces concepts for the sensor design and application of luminescent MOF materials in the field.
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