材料科学
铁电性
电介质
反铁电性
相变
掺杂剂
凝聚态物理
相(物质)
压电
正交晶系
四方晶系
钙钛矿(结构)
结晶学
兴奋剂
晶体结构
光电子学
复合材料
化学
有机化学
物理
作者
Hong Tao,Jie Yin,Chunlin Zhao,Lin Zhao,Bo Wu,Jian Ma,Daji Ergu
标识
DOI:10.1016/j.jeurceramsoc.2023.09.020
摘要
Sodium niobate (NN) lead-free perovskites have been concentrated on due to high performance and abundant phase structure. The complex structure evolution has become a hot topic of research for this kind of materials. In this work, antiferroelectric phase is recovered by introducing La3+ dopant from modified ferroelectric states, indicating reversible composition-induced antiferroelectric-ferroelectric (AFE-FE) phase transition in NN-based ceramics. Significantly, change tendency of decreasing first and then increasing appears for phase transition temperature with increasing La3+, which is different from general phenomenon for ions dopant. Antiferroelectric orthorhombic (Pbma) is induced from ferroelectric tetragonal (P4mm) with a transient state of paraelectric cubic (Pm3m) via enhancing La3+. Further, substitution on A-site and A/B-sites are revealed with low and high content of La3+, respectively, accompanied by decreased first and then increased oxygen vacancy. Moreover, obviously deteriorated piezoelectric response is observed along with poor domain switching due to the vanishing ferroelectric domain for FE-PE-AFE phase transition. Meanwhile, weak strain, piezoelectric and dielectric properties are observed for antiferroelectric phase with antiparallel dipoles, while enhanced strain and dielectric permittivity are gained around ferroelectric-paraelectric coexistence or paraelectric region originating from electric field-induced ferroelectric state from polar nanoregions. Thus, this work demonstrated an abnormal phase transition in NN-based ceramics, promoting the understanding of antiferroelectrics.
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