PdMo Bimetallene Coupled with MXene Nanosheets as Efficient Bifunctional Electrocatalysts for Formic Acid and Methanol Oxidation Reactions

In this study, we demonstrate a facile soft chemistry strategy for the in situ growth of two-dimensional (2D) ultrathin PdMo bimetallene tightly coupled with Ti₃C₂T_x MXene nanosheets (PdMo/Ti₃C₂T_x) using a robust stereoassembly process. The 2D PdMo bimetallene offers numerous unsaturated Pd atoms and simultaneously induces combined bimetallic alloy and strain effects, while the Ti₃C₂T_x matrix effectively optimizes the electronic structure of PdMo bimetallene via a face-to-face interface interaction and guarantees exceptional electrical conductivity. As a consequence, the newly designed PdMo/Ti₃C₂T_x nanoarchitecture expresses remarkable electrocatalytic properties for the formic acid and methanol electro-oxidation, in terms of large electrochemically active surface areas, ultrahigh catalytic activity, strong antipoisoning ability, and dependable long-term stability, all of which are better than those of conventional Pd nanoparticle catalysts supported by Ti₃C₂T_x and carbon matrices.