磁化
微晶
纳米材料
矫顽力
材料科学
煅烧
带隙
杂质
分析化学(期刊)
光催化
纳米技术
凝聚态物理
化学
催化作用
冶金
磁场
光电子学
物理
量子力学
生物化学
有机化学
色谱法
作者
Kolleti Venkatadri,D. Zarena
标识
DOI:10.1149/2162-8777/ad0dc1
摘要
Continuous efforts are being made on YFeO 3 (YFO) nanomaterial to improve the magnetization value in different ways for photocatalysis and magneto-optical application point of view because of low energy bandgap (1.8–2.8 eV). In this regard, we made solid solutions with Sr 2 Bi 4 Ti 5 O 18 (SBT) nanomaterial in an effort to increase the magnetization value of YFO nanomaterial. Here prepared the (1− x ) YFO + x SBT (where x = 0, 0.00125, 0. 0025, and 0.005) nanomaterials via sol-gel route, and thus obtained individually powders were calcined at 1050 °C/3 h. The single phase of YFO without any unreacted or impurity phases were observed up to x = 0.25 mol% via X-ray diffraction studies. Calculated average crystallite size as well as dislocation density suggesting that the improvement of crystalline nature YFO sample with an increase of SBT content in YFO. The improved magnetization value (4.121 emu g −1 ), which is 1.3 times higher than that of YFO (3.188 emu g −1 ), for the x = 0.25 mol% SBT in YFO was observed, however their coercivity (39.4 Oe) is almost similar for both samples. The computed optical bandgap was found to be reduced with an increase of SBT mol% in YFO. We draw the conclusion from this analysis that SBT in YFO (x = 0.25 mol%) will make promising candidates for various magnetic applications.
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