材料科学
极化率
电容器
极化(电化学)
铁电性
陶瓷
极地的
单独一对
电介质
耦合强度
凝聚态物理
光电子学
化学物理
复合材料
电压
电气工程
物理化学
化学
物理
有机化学
天文
分子
工程类
作者
Xiqi Chen,Zhigang Sun,Huanhuan Li,Jinjun Liu,Peng Li,Jinfeng Lin,Zhongbin Pan
标识
DOI:10.1016/j.jeurceramsoc.2023.11.036
摘要
Electrostatic capacitors as vital electronic components are extensively studied for applications in lightweight electrification systems. However, it is imperative to develop electrostatic capacitors with concurrently high breakdown strength and polarizability to achieve large energy densities. Herein, we design a weakly coupled relaxor ferroelectric ceramic of BaTiO3-K0.5Bi0.5TiO3-Bi(Ni2/3Nb1/3)O3 (BT-BKT-BNN). The introduction of BKT matrix with A-site lone pair effect, greatly increases saturated polarization strength. Additionally, incorporation of BNN with valence mismatched ions Ni2+ and Nb5+ hinders long-range polar coupling and resulted in the creation of polar nanoregions. By combining a high breakdown strength (Eb ~ 700 kV cm-1), large polarization (~ 30.7 µC cm−2), and negligible remnant polarization (< 2 µC cm−2), a remarkable energy density (Wrec) of 6.1 J cm−3 and an efficiency (η) of 87.7% are attained. Specifically, the system demonstrates a superb cycling stability, frequency-insensitive and good temperature stability. This article affords an effective strategy for tailoring high-performance relaxor ferroelectrics.
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