Enhancing corrosion resistance of mild steel in hydrochloric acid solution using 4-phenyl-1-(phenylsulfonyl)-3-thiosemicarbazide: A comprehensive study
腐蚀
盐酸
化学
冶金
材料科学
核化学
作者
Najeb Salman Abtan,A Sultan,Firas Farhan Sayyid,Ahmed A. Al‐Amiery,Ahed Hameed Jaaz,Tayser Sumer Gaaz,Samina Ahmed,A. I. Mustafa,Daoud Ali,Mahdi M. Hanoon,M Solomon,I Uzoma,J Olugbuyiro,O Ademosun,D Wang,Y Li,B Chen,L Zhang,B El-Haitout,I Selatnia
In the realm of materials science and corrosion mitigation, the utilization of inhibitors has garnered substantial attention for safeguarding metal assets.This research delves into the proficient utilization of 4-phenyl-1-(phenylsulfonyl)-3-thiosemicarbazide (PP-3-T) as a corrosion inhibitor for mild steel in hydrochloric acid (HCl) solutions, as evaluated through weight loss measurements.The investigation reveals that the incorporation of PP-3-T into the HCl medium engenders a significant enhancement in the corrosion resistance of mild steel, attributed to the formation of a protective barrier via PP-3-T molecule adsorption.A notable finding of this study is the independence of the corrosion inhibition efficiency on variables such as PP-3-T concentration, immersion time, and temperature.The best inhibition efficiency of 96.1% for mild steel immersed in 1 M HCl solution is achieved in the presence of 0.5 mM PP-3-T.Furthermore, the inhibitory effect diminishes significantly as immersion time is extended from 10 to 48 hours at a constant PP-3-T concentration, highlighting the time-sensitive nature of the inhibition process.Alterations in temperature within the range of 303 to 333 K exhibit negligible impact on inhibition efficiency,