化学
琥珀酰亚胺
硼氢化钠
吡咯烷酮类
盐酸
还原(数学)
内酰胺
有机化学
组合化学
催化作用
几何学
数学
作者
J. Hubert,J. B. P. A. Wijnberg,W. N. Speckamp
出处
期刊:Tetrahedron
[Elsevier]
日期:1975-01-01
卷期号:31 (11-12): 1437-1441
被引量:241
标识
DOI:10.1016/0040-4020(75)87076-1
摘要
One of the carbonyl functions of succinimides and glutarimides is selectively reduced by sodium borohydride in presence of hydrochloric acid yielding ω-carbinol-lactams. Some factors influencing the reduction process are discussed. Depending on the conditions pyrrolidinones, cyclic enamides or dimeric lactams are formed upon treatment of the ω-carbinol-lactams with acid.
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