Electron Matters: Recent Advances in Passivation and Applications of Black Phosphorus

Abstract 2D materials have experienced rapid and explosive development in the past decades. Among them, black phosphorus (BP) is one of the most promising materials on account of its thickness‐dependent bandgap, high charge‐carrier mobility, in‐plane anisotropic structure, and excellent biocompatibility, as well as the broad applications brought by the properties. In view of the electron configuration, the most unique feature of BP is the lone‐pair electrons on each P atom. The lone‐pair electrons inevitably cause high reactivity of BP, particularly toward water/oxygen, which greatly limits the practical application of BP under ambient conditions. The other side of the coin is that BP can serve as an electron donor to promote the construction of BP‐based hybrid materials and/or to boost the performance of BP or BP‐based hybrid materials in applications. Here, recent advances in passivation and application of BP by addressing the interaction between the lone‐pair electrons of BP and the other materials are discussed, and prospects for future research on BP are also proposed.