热解
催化作用
碳纳米纤维
碳纤维
碳纳米管
煤
材料科学
无定形碳
碳纳米管负载催化剂
化学工程
碳酸钾
无机化学
二茂铁
化学
有机化学
无定形固体
纳米技术
复合材料
电化学
物理化学
电极
工程类
复合数
作者
Xuemei Lv,Yongfa Zhang,Ying Wang,Guojie Zhang,Jun Liu,Yang Lu
标识
DOI:10.1016/j.jaap.2021.105400
摘要
Carbon nanotubes were successfully synthesized by Fe-K catalytic pyrolysis of coal. The co-pyrolysis of coal and ferrocene can only form fewer carbon nanotubes due to the few available carbon sources. Potassium carbonate can significantly eliminate the defects in the plane between the basic structural units of coal and promote the formation of carbon nanotubes, but its catalytic graphitization effect was limited when potassium carbonate was dry mixed with coal. In addition, the results show that Fe and K had a synergistic effect. Fe atoms and C atoms formed Fe-C solid solution during pyrolysis, K-based catalyst etched amorphous carbon atoms of coal, and finally Fe-K co-catalyzed the growth of a large number of carbon nanotubes with a higher degree of graphitization. The catalytic pyrolysis process had great impact on the aromatic structure and oxygen-containing functional group structure, but slight impact on the aliphatic structure of coal. The molten state of the catalyst during pyrolysis and its affinity for amorphous carbon was higher than that of graphitic carbon, leading to the migration of the catalyst and the change of crystal plane, which may be the reason for the formation of "carbon nanofiber-tube".
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