A novel intramolecular [2π+ 2π] photocycloaddition of di- and tetra-allylsilanes
利乐
分子内力
化学
药物化学
立体化学
作者
K. Nakanishi,Kazuhiko Mizuno,Yoshio Otsuji
出处
期刊:Journal of the Chemical Society [The Royal Society of Chemistry] 日期:1991-01-01卷期号: (2): 90-92被引量:19
标识
DOI:10.1039/c39910000090
摘要
Irradiation of di- and tetra-allylsilanes in the presence of 1,4-dicyanonaphthalene (1,4-DCN) in benzene afforded the intramolecular [2π+ 2π] photocycloadducts in good yields via(1,4-DCN–C6H6–Si-compound) triplexes.