纳米棒
光催化
材料科学
异质结
化学工程
吸附
可见光谱
纳米技术
催化作用
光电子学
化学
有机化学
工程类
作者
Xiaochun Ke,Jinfeng Zhang,Kai Dai,Ke Fan,Changhao Liang
出处
期刊:Solar RRL
[Wiley]
日期:2021-02-15
卷期号:5 (4)
被引量:207
标识
DOI:10.1002/solr.202000805
摘要
Photocatalytic CO 2 reduction to value‐added fuels is an appealing avenue in response to global warming and the energy crisis, but it still suffers from high energy barriers, low conversion efficiencies, and poor photostability. Herein, a novel S‐scheme SnNb 2 O 6 /CdSe–diethylenetriamine (SNO/CdSe–DET) heterojunction is designed by a microwave‐assisted solvothermal process, composed of 2D ultrathin SNO nanosheets (NSs) and amine‐modified CdSe–DET nanorods (NRs). The SNO/CdSe–DET composite without any co‐catalyst possesses a boosted performance in the solar‐driven photocatalytic conversion of CO 2 to CO, and the highest CO evolution rate achieved is 36.16 μmol g −1 h −1 , which is roughly 3.58 and 9.39 times greater than those of CdSe–DET and SNO under visible‐light illumination. Such a superior activity should be ascribed to the S‐scheme system, which benefits the separation of the photogenerated carriers and promotes the synergy between CdSe–DET NRs and SNO NSs by strong chemical‐bonding coordination. Meanwhile, DET can enhance CO 2 adsorption/activation and precisely regulate the surface reactive sites. This innovative work provides fresh insight into the development of highly efficient S‐scheme photocatalytic heterostructures for CO 2 reduction.
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