增塑剂
邻苯二甲酸盐
氯乙烯
材料科学
热稳定性
溶剂
极限抗拉强度
核化学
有机化学
化学
复合材料
聚合物
共聚物
作者
Dekai Liu,Yirui Shen,Phyu Thin Wai,Agus Haryono,Pingbo Zhang,Zhixin Nie,Guoqiang Jiang,Huihang Zhao,Minzhong Zhao
摘要
Abstract Recently, phthalates have been continuously banned in numerous fields by many countries. Therefore, the development of sustainable and efficient plasticizers has become particularly urgent. The waste cooking oil was used as the main raw materials in this study to synthesize an efficient plasticizer (acetylated‐fatty acid methyl ester‐trimellitic acid ester, AC‐FAME‐TAE). The structure of AC‐FAME‐TAE was characterized by FT‐IR and 1 H NMR. The performance of the poly(vinyl chloride) (PVC) plasticized by AC‐FAME‐TAE was tested and compared with those of the PVC plasticized with di‐2‐ethylhexyl phthalate (DOP) and EFAME (epoxy fatty acid methyl ester), respectively. DSC results indicated that AC‐FAME‐TAE had excellent plasticizing efficiency for PVC. The mechanical properties of PVC plasticized by AC‐FAME‐TAE were as comparable as PVC plasticized by DOP from the results of tensile test. In addition, the PVC plasticized by AC‐FAME‐TAE had excellent thermal stability and solvent resistance by the results of leaching test and TGA.
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