电解质
材料科学
乙二醇
聚氨酯
锂(药物)
化学工程
阻燃剂
离子电导率
六亚甲基二异氰酸酯
聚乙二醇
化学
电极
复合材料
物理化学
内分泌学
工程类
医学
作者
Jia Chen,Zhihong Liu,Jiyan Liu,Xueqing Liu,Ye Xue,Xueliang Jiang
标识
DOI:10.1016/j.matchemphys.2022.125763
摘要
An effective approach is proposed to enhanced the safety of lithium batteries by an intrinsic flame-retardant polyurethane (FR-PU) solid electrolyte, which is constructed by ethylene glycol methyl phosphonate ethylene glycol propionate (EMPEP), polyethylene glycol 800 (PEG800) and hexamethylene diisocyanate (HDI) through a simple polymerization reaction. The FR-PU not only displays benign flame retardancy with the limit oxygen index value of 27.6, but also exhibits excellent flexibility, sufficient mechanical strength and heat resistance which are beneficial to their dimensional stability. Infrared spectroscopy results reveal the complicated coordination relationship between FR-PU and lithium ion. The ionic conductivity of solid electrolyte with FR-PU containing 20 wt% lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI) can up to 1.51 × 10−4 Scm−1 at 70 °C. The FR-PU-20% Li solid electrolyte possesses a wide electrochemical stability window of 0–4.81 V (vs. Li+/Li). Moreover, the cells which fabricated with lithium iron phosphate (LiFePO4), FR-PU-20% Li, and Li anodes exhibits both superior discharge specific capacity and cycle performance (discharge specific capacity of 155.1 mAhg−1 and coulombic efficiency of 98.3% after 120 cycles at the rate of 0.2 C) at 70 °C. Therefore, FR-PU could be a promising candidate as a high performance polymer electrolyte to improve the safety of lithium batteries.
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