色素敏化染料
表面等离子共振
材料科学
复合数
阳极
退火(玻璃)
纳米颗粒
光电子学
电化学
图层(电子)
等离子体子
化学工程
纳米技术
电极
化学
复合材料
物理化学
工程类
电解质
作者
Peng Zhang,Fu-Chen Chu,Mengen Zhou,Bairui Tao,Fengjuan Miao
出处
期刊:Vacuum
[Elsevier BV]
日期:2023-11-08
卷期号:219: 112763-112763
被引量:9
标识
DOI:10.1016/j.vacuum.2023.112763
摘要
A new type of photoanode for dye-sensitive solar cells based on Ag/CdS/TiO2 natural dyes was designed and fabricated. Firstly, the mixed layer of CdS and TiO2 was prepared by high temperature annealing method, and the mixed layer was modified by Ag nanoparticles and sensitized by natural dyes to obtain the desired composite structure photoanode. The excellent localized surface plasmon resonance (LSPR) effect exhibited by Ag nanoparticles greatly enhances the electron-harvesting ability of the photoanode. The addition of CdS enhances the photosensitivity of the photoanode, diminishes electrons' recombination and enhances electrons' mobility. The final electrochemical test results show that the DSSC using the Ag/CdS/TiO2 composite structure photoanode and sensitized by natural dyes has reached a PCE of 0.68 %, compared with the DSSC with pure TiO2 photoanode the absorption range is wider, and the PCE has grown by 219 %.
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