Transition from silver-to copper-based screen printed SHJ solar cells

材料科学 化学 光学 纳米技术 物理 冶金
作者
S. Pingel,Fares Maarouf,Noah Wengenmeyr,Michael Linse,L. Folcarelli,Jörg Schube,S. Hoffmann,Sebastian Tepner,Jonas D. Huyeng,Andreas Lorenz,Florian Clement
出处
期刊:Solar Energy Materials and Solar Cells [Elsevier BV]
卷期号:287: 113593-113593 被引量:3
标识
DOI:10.1016/j.solmat.2025.113593
摘要

In this work, we demonstrate the possibility to reduce silver consumption for highly efficient silicon heterojunction (SHJ) cells by screen printing using low temperature paste based on silver, silver-coated copper or pure copper particles. The achieved grid fingers were characterized towards the line and contact resistance as well as the printed width. The most promising pastes with silver or silver-coated-copper particles allow printing of 35 μm narrow fingers with low line resistance of well below 10 Ω/cm. Simulations show that the achieved grid fingers, lead to very low silver consumption. Comparing cost to efficiency optimization shows that the most cost-effective cell has substantially lower efficiency. This might enable the introduction of alternative low silver or silver-free metallization techniques. To show the currently available options to save silver in screen printed busbarless SHJ cells, samples were produced with specific silver consumption of 7.5 mg/W and even below 5 mg/W if the rear side was realized with a pure copper paste. In another test, silver-based cells with same level of efficiency, improved bifaciality and reduced silver laydown (1/3 compared to reference) around 8 mg/W were successfully introduced into modules. • The silver utilization compares Ag consumption in Ag and AgCu pastes for SHJ cells. • Challenges in transition from Ag to AgCu pastes: fine line and contact resistivity. • Cost optimizations reduced efficiency by 0.4 % but lowers Ag consumption by 3 mg/W. • Low Ag consumption of less than 5 mg/W was achieved for Ag/Cu cells. • Advancements in technology will help to achieve Ag consumption goals for SHJ.
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