肉桂醛
催化作用
石墨烯
环己酮
材料科学
X射线光电子能谱
氧化物
拉曼光谱
化学工程
无机化学
光化学
化学
纳米技术
有机化学
工程类
物理
光学
作者
Renfeng Nie,Meng Miao,Weichen Du,Juanjuan Shi,Yingchun Liu,Zhaoyin Hou
标识
DOI:10.1016/j.apcatb.2015.07.015
摘要
In this work, N-doped reduced graphene oxides (NRGO) was synthesized via a facile urea-hydrothermal treatment of graphene oxide and used as support for ultrafine Pd nanoparticles (NPs). It was found that N in NRGO can improve the dispersion of Pd NPs. NRGO supported Pd catalyst (Pd/NRGO) is highly active and selective for the hydrogenation of CC bond in cinnamaldehyde and hydrogenation of phenol to cyclohexanone under mild conditions. X-ray diffraction, X-ray photoelectron spectra and transmission electron microscopy characterizations confirmed the interaction between NRGO and Pd enhanced with the amount of N atom in NRGO. Raman spectroscopy of adsorbed cinnamaldehyde on Pd/NRGO suggested that NRGO played a positive role in the selective activation of CC bond in cinnamaldehyde.
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