Adsorption and desorption capacities of various macroporous resins to polyphenols(EGCG, ECG) and caffeine in green tea extract were examined in an effort to remove caffeine from it.Results showed that RS-1 resin exhibited the best decoloration effect, and RX-2 resin exhibited strong selective adsorption capacity to caffeine, thereby providing an effective approach for removing caffeine from green tea extract.After the two-step resin separation, the relative contents of EGCG and ECG could reach 74.72% and 17.45% from 49.78% and 11.56%, with the yields of about 78.31% and 83.46%, respectively, and the caffeine content could be reduced to about 0.2%.