The nickel layer structures of nickel foam at different stages in theelectrodepositionprocess were observed, and it was found that the nickel layers after both electroplating and treatmentin air at 600 ℃ for 4 min possessed the microcrystalline structures with obvious flaw, but become thecompact nickel crystal ones with even surface and big crystal particles after enough sintering treatment inNH3 decomposition atmosphere at 85℃ or 980℃ for 40 min.