腐蚀
离子液体
材料科学
碳钢
化学工程
溶解度
离子键合
碳纤维
缓蚀剂
无机化学
电化学
冶金
化学
离子
复合材料
物理化学
有机化学
催化作用
电极
工程类
复合数
作者
Fengting Li,Zhikun Wang,Yongquan Zhou,Lizhi Liu,Yueqi Liu,Li Wang,Chunling Li,Huafeng Zhu,Shuang-Qing Sun,Songqing Hu
标识
DOI:10.1016/j.corsci.2023.111541
摘要
Chemical modification is effective in improving the corrosion inhibition efficiency of carbon dots (CDs) on steel. Here, the imidazolium ionic liquids (IL) modified-CDs (IL-CDs) are synthesized and proved to be mixed-type corrosion inhibitors. The IL increases the pyrrole N content and facilitates the formation of a denser inhibitor film. Molecular simulations confirm that the IL reduces the π-π interaction between CDs, endowing IL-CDs with higher water solubility and better corrosion inhibition effect than CDs. The lower orbital energy gap and larger positive electrostatic potential distribution enable the inhibition efficiency of IL-CDs of 97.11% in 1 M HCl, much superior to CDs (90.80%).
科研通智能强力驱动
Strongly Powered by AbleSci AI