Multiscale analysis of long-term mechanical and durability behaviour of two alkali-activated slag-based types of concrete

Although alkali activated concretes (AACs) are promising for reducing the carbon emissions of concrete, in order to enable their wide application it is vital to understand their long-term behaviour. Herein, we report the development of mechanical properties of a ground granulated blast furnace slag (GGBFS)-based AAC and a binary fly ash (FA) /GGBFS-based AAC exposed to 55% relative humidity and 20 °C up to the age of 5 years. For comparison, two ordinary Portland cement (OPC) concretes were monitored for 3.5 years. For the GGBFS-based AAC, after an initial decrease within the first 6 months the elastic compressive modulus stabilized, while its tensile splitting strength continued to decrease for the tested period of 5 years. The binary AAC showed a continuous decrease in its tensile splitting strength for 5 years and a reduction in its compressive strength after 2 years. No decreases in mechanical properties were observed in OPC-based concretes. To reveal underlying mechanisms, additional analyses were performed. Permanent degradation was observed in both AACs; the binary AAC mainly suffered from carbonation, and the GGBFS-based AAC showed microcracking. These cracks were probably caused by drying shrinkage and drying-induced chemical changes. Based on the measured mechanical properties of AAC, crack widths and stiffness of reinforced AAC beams under bending were analytically evaluated and compared to experiments. Decreases in bending stiffness and increases in crack width were observed for reinforced AAC beams tested at later ages. A bimodular approach is proposed to predict the reduction of bending stiffness in the studied AACs over time. These findings are relevant to understand serviceability limit states of reinforced AACs.