异构化
查尔酮
光致变色
光化学
化学
环加成
Crystal(编程语言)
光异构化
分子
结晶学
立体化学
有机化学
催化作用
计算机科学
程序设计语言
作者
Yuan Yue,Yuanhong Shu,Kaiqi Ye,Jingbo Sun,Cheng Liu,Shuting Dai,Liuyang Jin,Chengde Ding,Ran Lu
标识
DOI:10.1002/chem.202203178
摘要
Abstract Three groups of chalcone derivatives and their analogues involving halogen atoms (X=F, Cl, Br) have been synthesized. Firstly, the nearly planar acyclic chalcone derivatives were inclined to undergo photo‐induced stereospecific [2+2] cycloaddition, which triggered the crystals to exhibit macroscopic motions of bending or cracking. In particular, the single‐crystal‐to‐single‐crystal transformation happened upon UV irradiation of the crystals, which was helpful for the understanding photomechanical effects. Cyclic 3,4‐dihydronaphthalene‐based chalcone analogues possess a more twisted conformation, and they tend to undergo trans‐cis isomerization. No photomechanical effect was observed for the crystals of the cyclic chalcone analogues due to the lower isomerization rate. The twist degree of chroman‐based molecules was in between of the first two, [2+2] cycloaddition and trans‐cis isomerization simultaneously took place in crystals. Photo‐induced bending and twisting were observed for the crystals of chroman‐based chalcone analogues. Therefore, the differences in molecular dihedral angles in α,β‐unsaturated ketones were responsible for their photochemical characters and in turn to tune the photomechanical effects. In this work, a bridge between the molecular structures and solid‐state photochemical reactions triggered photomechanical crystals is built.
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